Bichan Nataliya Gennadievna

Position: 
Senior researcher
Degree: 
Phd in chemistry
Phone: 
+7 (4932) 336990
Awards and honors:

- Winner of the competition for receiving a scholarship of the President of the Russian Federation for State Support of Young Russian Scientists with a PhD degree, 2020;
- First-Class Diploma for a poster presentation at the “XVII International Conference on Spectroscopy of Coordination Compounds, 2020”;
- Diploma for the best oral report at the “XVI International Conference on Spectroscopy of Coordination Compounds, 2019”;
- Winner of the 2019 Competition of the most relevant papers “Choice of the Editorial Board” (Russian Journal of Inorganic Chemistry).
- Winner of the prize for the best publication in the journals issued by the International Academic Publishing Company “Science/Interperiodica”, 2015.
- Winner of the G.A. Krestov scholarship of G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 2015.
- Winner of the competition for receiving a grant for financial support of young scientists of the ISC RAS, 2014, 2015.
- Diploma of the Government of Ivanovo Region for the High-Level of Research and Significant Contribution to the Development of Science and Innovations in Ivanovo Region, 2012.
- Winner of the G.A. Krestov scholarship of G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 2012.
- Diploma for the best report in the “Liquid Crystals and Nanomaterials” session of the “Young Science in the Classical University-2011” Festival.
- Diploma for the best oral report at the V Regional Conference of Young Scientists “Theoretical and Experimental Chemistry of Liquid Phase Systems” (Krestov Readings), 2010.
- Diploma for the best presentation of the oral report at the VIII Regional Student Scientific Conference “Science Days-2010” “Fundamental Sciences for the New Century Specialist”.
- Winner of the first prize at the VII Regional Student Scientific Conference “Science Days-2009” “Fundamental Sciences for the New Century Specialist”.

His research interests:

- Synthesis of macroheterocyclic complexes of d-metals;
- Synthesis of fullerene derivatives;
- Self-assembly of supramolecular systems based on porphyrins/phthalocyanines, research into the mechanisms underlying these processes;
- Design of donor-acceptor systems with photo-induced electron transfer;
- Study of applied (photoactive and antibacterial) properties of macroheterocyclic complexes.

Participation in grants and programs:

1. Photoactive supramolecular systems based on porphyrin complexes of d-metals as components of photovoltaic devices (grant of the President of the Russian Federation for State Support of Young Russian Scientists with a PhD Degree No. МК-1741.2020.3, head of the project).
2. New supramolecular complexes based on cobalt porphyrins as components providing materials with photoactive and antimicrobial properties (RFBR No. 18-43-370023_r_а, 2018-2020).
3. A new class of donor-acceptor complexes of metalloporphyrins with fullerene derivatives producing a strong magnetocaloric effect and possessing the property of photoinduced charge separation (RFBR No. 18-43-370022_r_а, 2018-2020).
4. New photoactive donor-acceptor systems based on macroheterocyclic complexes of d-metals for creating modifying films on titanium photoanodes (RFBR No. 16-03-00631_А, 2016-2017, head of the project).
5. Synthesizing and finding of effective supramolecular compositions with antibacterial action based on macroheterocyclic complexes of manganese and cobalt (RFBR No. 15-43-03013-r-tsentr-a, 2015-2016).
6. Donor-acceptor porphyrin-fullerene polyades for hybrid solar cells (RFBR No. 15-03-00646_А, 2015-2017).
7. Program of Fundamental Research of the Presidium of the Russian Academy of Sciences No. 8 "Directional synthesis of inorganic substances with specified properties and creation of functional materials based on them" (2014).
8. Program of Fundamental Research of the Presidium of the Russian Academy of Sciences No. 14 "Detection, isolation, and determination of the structure of pi-cation-radical intermediates of catalytic reactions of metalloporphyrins" (2015-2017).

The most important publications:

1. E.N. Ovchenkova, N. G. Bichan, A. A. Tsaturyan, N. O. Kudryakova, M. S. Gruzdev, F. E. Gostev, I. V. Shelaev, V. A. Nadtochenko, T. N. Lomova Effects of a Central Atom and Peripheral Substituents on Photoinduced Electron Transfer in the Phthalocyanine-Fullerene Donor-Acceptor Solution-Processable Dyads // J. Phys. Chem. C 2020, 124, 4010−4023, https://doi.org/10.1021/acs.jpcc.9b11661

2. A. A. Ksenofontov, M. M. Lukanov, N. G. Bichan, I. A. Khodov, N. O. Kudryakova, K. V. Ksenofontova, E. V. Antina Non-covalent supramolecular systems with photoinduced electron transfer based on zinc bis(dipyrromethenate)s and C60 // Dyes and Pigments, 2020, 108918, https://doi.org/10.1016/j.dyepig.2020.108918

3. N. G. Bichan, E. N. Ovchenkova, A. A. Tsaturyan, T. N. Lomova Spectral properties of supramolecular systems based on cobalt(II)/manganese(III) phthalocyanine and fullero[60]pyrrolidines with PET //  New Journal of Chemistry, 2020, 44, 11262, https://doi.org/10.1039/D0NJ02166K

4. E. N. Ovchenkova, N. G. Bichan, A. A. Ksenofontov, T. N. Lomova. New dyads based on trifluoromethylated phthalocyanine derivatives and substituted fullerene with possible application photoinduced electron transfer // Journal of Fluorine Chemistry, 2019. V. 224, P. 113-120. https://doi.org/10.1016/j.jfluchem.2019.06.002

5. E.N. Ovchenkova, N.G. Bichan, N.O. Kudryakova, T.N. Lomova Study of the photoresponse of a titanium anode coated with solution-processed fullerene-containing metal porphyrin/phthalocyanine films Journal of Molecular Liquids // Journal of Molecular Liquids. 2019. № 15. V. 208. P. 382-388, https://doi.org/10.1016/j.molliq.2019.01.025

6. A.A. Ksenofontov, N. G. Bichan, I.A. Khodov, E. V. Antina, M. B. Berezin, Anatoly I. Vyugin Novel non-covalent supramolecular systems based on zinc(II) bis(dipyrromethenate)s with fullerenes // Journal of Molecular Liquids 269 (2018) 327–334, https://doi.org/10.1016/j.molliq.2018.08.069

7. N.G. Bichan, E.N. Ovchenkova, N.O. Kudryakova, A.A. Ksenofontov, M.S. Gruzdev, T.N. Lomova. Self-assembled via axial coordination cobalt(II)porphyrin–fulleropyrrolidine triads with photoinduced electron transfer // New J. Chem. 2018. V. 42 P. 12449 https://doi.org/10.1039/c8nj00887f

8. E. N. Ovchenkova, N. G. Bichan, N. O. Kudryakova, A. A. Ksenofontov, T. N. Lomova Synthesis and properties of the novel (tetraazaporphinato)/(phthalocyaninato) manganese(III) – Pyridyl-substituted [60] fulleropyrrolidine dyads assembled through donor–acceptor bonding // Dyes and Pigments V. 153. 2018. P. 225–232 https://doi.org/10.1016/j.dyepig.2018.02.023

9. N.G. Bichan, E.N. Ovchenkova, N.O. Kudryakova, T.N. Lomova. Cobalt(II) porphyrin axially coordinated with 2′-(pyridin-4-yl)-5′-(pyridin-2-yl)-1′-(pyridin-2- ylmethyl)-2′,4′-dihydro-1′H-pyrrolo[3′,4′ : 1,2](C60-Ih) [5,6]fullerene: formation, chemical structure, and spectroscopic properties // J. Coord. Chem. 2017. V. 70. P. 2371-2383. http://dx.doi.org/10.1080/00958972.2017.1335867

10. E. N. Ovchenkova, N. G. Bichan, T. N. Lomova. New soluble octakis-substituted Co(II) phthalocyanines: synthesis, spectra, supramolecular chemistry // Dyes and Pigments 2016. V. 128. P. 263-270. http://dx.doi.org/10.1016/j.dyepig.2016.02.004

11. N. G. Bichan, E. N. Ovchenkova, V. A. Mozgova, N. O. Kudryakova,M. S. Gruzdeva, T. N. Lomova Mechanism of the Self-Assembly of Donor–Acceptor Triads Based on Cobalt(II) Porphyrin Complex and Fullero[60]pyrrolidine, According to Data Obtained by Spectroscopic and Electrochemical Means // Russian Journal of Physical Chemistry A, 2020, Vol. 94, No. 6, pp. 1159–1166. https://doi.org/10.1134/S0036024420060060

tolylporphyrin and substituted fullero[60]pyrrolidine. 2020. A–I. https://doi.org/10.1142/S1088424620500406

12. T.N. Lomova, V.V. Korolev, N.G. Bichan, E.N. Ovchenkova, A.G. Ramazanova, O.V. Balmasova, M.S. Gruzdev. New Paramagnets Based on Nanocarbon and Cobalt(II)Porphyrin: Magnetocaloric Effect and Specific Heat Capacity // Synthetic Metals, 2019. V. 253, P. 116-121. https://doi.org/10.1016/j.synthmet.2019.05.004

ORCID ID: 0000-0003-0889-913X

Scopus ID: 55321314200

Researcher ID is: C-3012-2017

main stages of research and teaching:

Education:
2005-2009: Bachelor's degree in standardization, certification and metrology (degree with honours), Ivanovo State University of Chemistry and Technology, Russia;
2005-2010: qualification of an Engineer in Standardization and Certification (degree with honours), Ivanovo State University of Chemistry and Technology, Russia;
2010-2013: postgraduate student, G.A. Krestov Institute of Solution Chemistry RAS.
Career:
2010-2013: Intern Researcher at G.A. Krestov Institute of Solution Chemistry RAS;
2013-2014: Junior Researcher at G.A. Krestov Institute of Solution Chemistry RAS;
2014-2018: Researcher at G.A. Krestov Institute of Solution Chemistry RAS;
2018 – present: Senior Researcher at G.A. Krestov Institute of Solution Chemistry RAS.