Kinetics of Mn(III)tetraazaporphyrin/C60-pyridyl supramolecular system formation

статья
Авторы публикации: 
Ekaterina N. Ovchenkova, Nataliya G. Bichan, Tatyana N. Lomova
Журнал: 
Tetrahedron
Год публикации: 
2015
Том/страницы: 
71/ 6659-6664

The reaction of (octakis(4-tert-butyl-phenyl)tetraazaporphyrinato) manganese(III) acetate ((AcO)
MnTAP(p-t-BuC6H4)8) with 20-(4-pyridyl)-50-(2-pyridyl)-10-(3-pyridylmethyl)-pyrrolidino[30,40:1,2][60]
fullerene (Py3F) in toluene was studied by methods of chemical kinetics and UV, visible, IR and 1H NMR
spectroscopy. The interaction is found to result in the formation of 1:1 donor-acceptor complex whose
structure was determined. A negative value of a complex formation order with respect to Py3F was
established and explained. The kinetic equation can be used in the development of technology of metal
tetraazaporphyrin-fullerene dyad production.

Опубликовано:
Бичан Наталия Геннадьевна
(16.05.2017)