The Direct Synthesis of 2-N-methyl-5,10,15,20-tetrakis(4′-sulfophenyl)-2- aza-21-carbaporphyrin J-aggregates

статья
Авторы публикации: 
Sheinin V. B., Kulikova O. M., Aleksandriiskii V. V., Koifman O. I.
Журнал: 
Macroheterocycles
Год публикации: 
2016
Том/страницы: 
V. 9, № 4. -- P. 353-360.

Here we present the way of synthesis of very stable J-aggregates based on water-soluble 2-N-methyl-5,10,15,20-tetrakis-(4′-sulfophenyl)-2-aza-21-carbaporphyrin zwitter-ion, which are formed as the main product of 2-N-methyl-5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin sulfonation by sulfuric acid. J-Aggregates and corresponding monomer were obtained for the first time and characterized using UV-Vis, 1H NMR, MALDI-TOF, ESI-MS analysis.

 

Опубликовано:
Зданович Сергей Антонович
(11.04.2017)