Influence of the composition of aqueous-amide solvents on enthalpic characteristics of L-proline dissolution at T=298.15 K

статья
Авторы публикации: 
Smirnov V. I., Badelin V. G.
Журнал: 
Journal of Molecular Liquids
Год публикации: 
2016
Том/страницы: 
V. 220. --P. 21-25.

The dissolution enthalpies of L-proline in aqueous solution of formamide, N-methylformamide and N,N-dimethylacetamide with a mole-fraction of amides from x(2) = (0 to 0.35) have been measured at T = 298.15 K. The results obtained have been used to calculate the standard enthalpies (Delta H-sol degrees) and transfer (Delta H-tT degrees) of L-proline from water into mixtures as well as the enthalpy coefficients of pairwise interaction (h(xy)) of the solute with amide in aqueous solutions. The interdependence between enthalpy characteristics of L-proline dissolution (transfer) and the composition of (water + amide) mixtures has been established. Comparison of the resulting data with those obtained earlier for L-phenylalanine and L-tryptophan in the same mixed solvents at 298.15 K has been made.

Опубликовано:
Колкер Римма Семеновна
(22.10.2021)