Influence of structural and solvation factors on the spectral-fluorescent properties of alkyl-substituted BODIPYs in solutions

статья
Авторы публикации: 
Bumagina N. A., Antina E. V., Berezin M. B., Kalyagin A. A.
Журнал: 
Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy
Год публикации: 
2017
Том/страницы: 
V. 173. -- P. 228-234.

The spectral-fluorescent properties of alkyl-substituted BODIPYs 1-5 in organic solvents were investigated. The alkyl-substituted BODIPYs 1-5 exhibit intense chromophoric properties (Ig epsilon = 4.60-5.00). Relative fluorescence quantum yield of studied compounds reaches 66-100% and weakly dependent on the structural and solvation effects. Introduction of methyl, propyl, amyl and heptyl substituents in the 2,6-positions of the pyrroles the results in a significant red shift (22-29 nm) in the electronic absorption and fluorescence spectra.

Опубликовано:
Колкер Римма Семеновна
(21.09.2021)