Smirnov Valeriy Igorevich

Position: 
Senior Researcher
Degree: 
Phd in chemistry
Academic title: 
Senior Researcher
E-mail: 
vis@isc-ras.ru
Subdivision: 
Laboratory "Thermodynamics of nonelectrolyte and biological substance solutions"
Research interests:

Thermodynamics of solutions of biologically active substances (amino acids and peptides) in aqueous and aqueous-organic media;

Intermolecular interactions in solutions.

Participation in grants and programs:
  • RFBR grant No. 18-03-01032 "Regularities of interaction of synthetic peptides with micelles simulating biological membranes: thermodynamic and structural aspects", participant;
  • RFBR grant No. 18-43-370018-r_a "Effects of binding of medicinal ligands to amino acids and peptides upon changes in their structure and acidity of the medium as a basis for the development of regulators of protein transport function", participant.
The most important publications:

The complete list of publications, see at ORCID ID: http://orcid.org/0000-0003-4256-4931.
Among the most important publications are the following

  1. V.I. Smirnov, V.G. Badelin. Dependence of the Enthalpies of Alanyl-alanine Dissolution on the Composition of Mixed Water + Acetone and Water + DMSO Solvents at 298.15 K. // Russ. J. Phys. Chem. A, 89/8 (2015)1311–1315. https://link.springer.com/article/10.1134/S0036024415080294
  2. V.G. Badelin, V.I. Smirnov. Thermodynamics of DL-Alalnyl-DL-Asparagine Dissolution in Water–Organic Mixtures at 298.15 K. // Russ. J. Phys. Chem. A, 89/10 (2015) 1796–1800. https://link.springer.com/article/10.1134/S0036024415100039
  3. V.I. Smirnov, V.G. Badelin. Influence of the composition of water–organic mixtures and the properties of organic solvents on thermochemical characteristics of l-methionine dissolution at 298.15 K. // Thermochimica Acta 616 (2015) 20–26. http://dx.doi.org/10.1016/j.tca.2015.08.006
  4. V.I. Smirnov, V.G. Badelin. Enthalpies of L-proline dissolution in aqueous solution of N, N-dimethylformamide at 293.15–308.15 K. //Thermochim. Acta 606 (2015) 41–44. http://dx.doi.org/10.1016/j.tca.2015.03.007
  5. V.I. Smirnov, V.G. Badelin. Enthalpy Characteristics of the Dissolution of L-Valine in Water/Formamide Mixtures at 298.15 K. // Russ. J. Phys. Chem. A, 90 (2016) 2165–2169. https://link.springer.com/article/10.1134/S0036024416110261
  6. V.I. Smirnov, V.G. Badelin. Influence of the composition of aqueous-amide solvents on enthalpic characteristics of L-proline dissolution at T= 298.15 K.// J. Mol. Liquids 220 (2016) 21–25. http://dx.doi.org/10.1016/j.molliq.2016.04.033
  7. V.I. Smirnov, V.G. Badelin. Thermochemical Characteristics of the Dissolution of D-Valine in Aqueous Solutions of Some Amides at T = 298.15 K. // J. Chem. Ing. Data. 89 (2016) 1593-1780. http://dx.doi.org/10.1021/acs.jced.5b01087
  8. V.I. Smirnov, V.G. Badelin. Enthalpy Characteristics of L-Proline Dissolution in Certain Water–Organic Mixtures at 298.15 K.// Russ. J. Phys. Chem. A, 91 (2017) 84–88. https://link.springer.com/article/10.1134/S0036024416120037
  9. V.I. Smirnov, V.G. Badelin. Thermochemical characteristics of 4-OH-L-proline and L-proline dissolution in (H2O + alcohol) mixtures at T=298.15 K. // J. Mol. Liquids 229 (2017) 198–202. http://dx.doi.org/10.1016/j.molliq.2016.12.025
  10. V.I. Smirnov, V.G. Badelin. Thermodynamic characteristics of trans-4-hydroxy-L-proline dissolution in some (water + amide) mixtures at T=298.15 K.// Thermochim. Acta 653 (2017) 27-31. http://dx.doi.org/10.1016/j.tca.2017.03.022
  11. V.I. Smirnov, V.G. Badelin. Thermodynamic Characteristics of the Dissolution of Glycine, Glycylglycine and Glycylglycylglycine in Aqueous Solutions of Sodium Dodecyl Sulfate at Т = 298.15 K. // Russ. J. Phys. Chem. A. 91/9 (2017) 1681–1684. https://link.springer.com/article/10.1134/S0036024417090291
  12. V.I. Smirnov, V.G. Badelin. Influence of N-methyl substitution in the glycine molecule on its enthalpic dissolution characteristics in mixed aqueous-amide solvents at T = 298.15 K. // J. Mol. Liquids 255 (2018) 471–475. https://doi.org/10.1016/j.molliq.2018.01.124
  13.  V.I. Smirnov, V.G. Badelin. Influence of the composition of aqueous-alcohol solvents on enthalpic characteristics of L-glutamine dissolution at T = 298.15. // J. Mol. Liquids 258 (2018) 253–257. https://doi.org/10.1016/j.molliq.2018.03.013
  14. V.I. Smirnov, V.G. Badelin. Thermodynamic Parameters of the Dissolution of 4-  Hydroxy-L-Proline and L-Phenylalanine in Mixed Aqueous Solvents at 298 K. Russ. // J. Phys. Chem. A. 92/1 (2018) 93–98. https://link.springer.com/article/10.1134/S0036024417120287
  15. V.I. Smirnov, V.G. Badelin. Thermochemistry of the Dissolution of Dipeptides Containing DL- α -Alanine in Aqueous Solutions of Sodium Dodecyl Sulfate at 298.15 K. Russ. // J. Phys. Chem. A. 92/5 (2018) 900–904. https://link.springer.com/article/10.1134/S003602441805028X
  16.  V.G. Badelin, V.I. Smirnov. Effect of N -Methyl Substitution in the Glycine Molecule on the Enthalpy of Dissolution in Mixed Water-Alcohol Solvents at 298.15K. // Russ. J. Phys. Chem. A. 92/7 (2018) 1299–1303. https://link.springer.com/article/10.1134/S0036024418070063
  17. V.I. Smirnov, V.G. Badelin. Similarity and differences of the thermochemical charac-teristics of L-glutamine dissolution in aqueous solutions of some acetamides and forma-mides at T = 298.15 K. // J. Mol. Liquids 285 (2019) 84–88. https://doi.org/10.1016/j.molliq.2019.04.099
  18.  V.I. Smirnov, V.G. Badelin. The effect of the side chain structures on the energy of intermolecular interactions of α-amino acids with some formamides in aqueous solutions at T = 298.15 K. // J. Mol. Liquids 275 (2019) 474–477. https://doi.org/10.1016/j.molliq.2018.11.065
  19. V.I. Smirnov, V.G. Badelin. Enthalpy Characteristics of Dissolving  N -Methylglycine in Some Aqueous–Organic Mixtures at 298.15 K. // Russ. J. Phys. Chem. A. 93/8 (2019) 1465–1470. https://doi: 10.1134/S0036024419080296
  20.  V.I. Smirnov, V.G. Badelin., V. P. Barannikov, M. S. Kurbatova. Influence of   the compositon of (H2O + SDS) mixtures on interaction energy of DL-α-alanyl-DL-α-valine and DL-α-alanyl-DL-α-norleucine with SDS micelles at T=298.15 K. // Journal of Solution Chemistry, 48 (2019)1309–1317. http://link.springer.com/article/10.1007/s10953-019-00910-1
  21.  V. I. Smirnov. Thermochemical investigation of L-glutamine dissolution processes in    aqueous co-solvent mixtures of acetonitrile, dioxane, acetone and dimethyl sulfoxide at T=298.15 K. // J. Chem. Thermodyn. 150 (2020). https://doi.org. :10.1016/j.jct.2020.106227
  22.  V. I. Smirnov. Thermochemistry of the Dissolution of L-Threonine in Acetonitrile, 1,4-Dioxane, Acetone, and Dimethylsulfoxide Aqueous Solutions at  Т  = 298.15 K. // Russ. J. Phys. Chem. A. 94/10 (2020) 2042–2046. http://link.springer.com/article/10.1134/S0036024420100271