Смирнов Валерий Игоревич

Должность: 
Старший научный сотрудник
Ученая степень: 
Кандидат химических наук
Ученое звание: 
Старший научный сотрудник
Награды, почетные звания:

Почетная грамота Президиума РАН

Научные интересы:

Термодинамика растворов биологически-активных веществ (аминокислот и пептидов) в водных и водно-органических растворителях.

Участие в грантах и программах:

- Грант РФФИ №07-03-00369-а «Гидрофобные и сольватационные эффекты в структурно-термодинамических характеристиках природных аминокислот и пептидов в растворах» (2007-2009)

- Грант РФФИ №11-03-00013-а «Специфика взаимодействия ароматических и гетероциклических природных аминокислот и пептидов с полифункциональными органическими молекулами в водных растворах при образовании молекулярных комплексов и конъюгатов» (2011-2013)

- Грант РФФИ №15-43-03003_р_центр_а «Структурно-термодинамические эффекты при взаимодействии аминокислот и пептидов с липополисахаридами в растворах как характеристики пептид-мембранного связывания  для разработки антибиотиков нового поколения» (2015-2017).

Наиболее важные публикации:

Наиболее важные публикации за 2003-2016 г.г.

Список основных публикаций приведен

на сайте ORCID ID: http://orcid.org/0000-0003-4256-4931

 

В том числе статьи:

 

  1. V.I. Smirnov, V.G. Badelin. The Enthalpy of Solution of Glycine in w-Propanol-Water and iso-Propanol-Water Mixtures at 298.15 K. Russ. J. Phys. Chem. 77/5 (2003)713-716. http://elibrary.ru/item.asp?id=17270281
  2. V.I. Smirnov, I. N. Mezhevoǐ, V.G. Badelin. The enthalpies of solution of DL-α-alanine in water-alcohol mixtures at 298.15 K. Russ. J. Phys. Chem. A. 78/2 (2004) 214-217. http://elibrary.ru/item.asp?id=17361754
  3. V.I. Smirnov, V.G. Badelin. Thermochemistry of Dissolution of Glycine, Glycylglycine, and Diglycylglycine in a Mixed Solvent Water-Dimethyl Sulfoxide at 298.15 K. Biophysics, 49/3 (2004) 375-380.
  4. V.I. Smirnov, V.G. Badelin, Solvation of Glycine and Its Oligomers in a Water–Acetonitrile Binary Solvent at 298.15 K. Russian Journal of Physical Chem. 79/4 (2005) 583–586. http://elibrary.ru/item.asp?id=9138856
  5. V.K Abrosimov., V.I Smirnov., E.V Ivanov., Yu.A Lebedev. Enthalpy of solution of tetramethyl-bis-urea (mebicarum) in light and heavy water and methanol isotopomers at 298.15 K. Russ. J. Phys. Chem. A. 79/11 (2005) 1878-1880. http://elibrary.ru/item.asp?id=9143435\
  6. V.I. Smirnov, V.G. Badelin, The Enthalpies of Solution and Solvation of Glycine in Mixed Water–Formamide Solvents at 298.15 K. Russ. J.Phys. Chem. 80/3 (2006)357–360. https://link.springer.com/article/10.1134/S0036024406030095
  7. V. I. Smirnov, I. N. Mezhevoi, and V. G. Badelin. The Enthalpies of Solution of DLa-Alanine in Water–Organic Solvent Mixtures at 298.15 KRussian Journal of Physical Chem. 80/5 (2006) 672–677. https://link.springer.com/article/10.1134/S0036024406050025
  8. E. V. Ivanov, V. K. Abrosimov and V. I. Smirnov. Enthalpies of transfer of urea and methyl-substituted ureas from water to methanol at 298.15K. Thermochim. Acta 449 (2006) 90-92. http://dx.doi.org/10.1016/2006ivaabr0
  9. V. I. Smirnov, I. N. Mezhevoi, and V. G. Badelin. The Thermochemical Characteristics of Solution of DL-a -Alanylglycine and DLa-Alanyl-DLa-Alanine in Water–Organic Solvent Mixtures at 298.15 K. Russ. J. Phys. Chem. A. 81/8 (2007) 1245-1249.  https://link.springer.com/article/10.1134/S0036024407080122
  10. V. I. Smirnov, I. N. Mezhevoi, and V. G. Badelin THE THERMOCHEMICAL CHARACTERISTICS OF SOLUTION OF DL-α-ALANYLGLYCINE AND DL-α-ALANYLALANINE IN WATER-ALCOHOL MIXTURES AT 298.15 K. Russ. J. Phys. Chem. A, 81/5 (2007) 727–730. http://elibrary.ru/item.asp?id=9536848
  11. E. V. Ivanov, V. K. Abrosimov, V. I. Smirnov. Enthalpies of solution of 1,1,3,3-tetramethylurea in normal and branched alkanols (C2 C4) at 298.15 K. J. Chem. Thermodyn. 39 (2007) 1614-1619. http://www.sciencedirect.com/science/article/pii/S002196140700081X
  12. V.I. Smirnov, V.G. Badelin, Enthalpies of Solution of L–L- and D–D- Isomers of Valine in Aqueous Alkanols at 298.15 K. J Solut. Chem 37(2008) 1419–1424. https://link.springer.com/article/10.1007/s10953-008-9313-z
  13. V.I. Smirnov, V.G. Badelin, Enthalpies of solution of glycylglycine and diglycylglycine in aqueous alcohols at 298.15K. Thermochim. Acta 471 (2008) 97–99. http://dx.doi.org/10.1016/j.tca.2008.01.02 
  14. V.I. Smirnov, V.G. Badelin, The Enthalpy of Solution of DL-a-Alanyl-DL-a-Valine Depending on the Composition of Water–Alcohol Binary Solvents at 298.15 K. Russian J. Phys. Chem. A, 82/12 (2008) 2069–2073. https://link.springer.com/article/10.1134/S0036024408120170
  15. E.V. Ivanov, V.I.Smirnov, Abrosimov V.K. Effect of intra-molecular cyclization on the enthalpies of solvation of tetramethylurea in water and  alkanols at 298.15 K. Thermochimica Acta. 475 (2008) 72-75. http://dx.doi.org/10.1016/j.tca.2008.07.001
  16. E.V. Ivanov, V.I.Smirnov, Abrosimov V.K. Addendum to "Effect of intramolecular cyclization on the enthalpies of solvation of tetramethylurea in  water and alkanols at 298.15 K". Thermochimica Acta. 479 (2008) 62-63. http://www.sciencedirect.com/science/article/pii/S0040603108002785
  17. E.V. Ivanov, V.I.Smirnov. Enthalpies of solution of N,N,N0,N0-tetramethylurea in amides,dimethylsulphoxide, and acetone at 298.15 K. J. Chem. Thermodynamics 40 (2008) 1342–1345. https://inis.iaea.org/search/search.aspx?orig_q=RN:40016672
  18. В.И.Смирнов, В.Г.Баделин. ЭНТАЛЬПИИ РАСТВОРЕНИЯ L- -АЛАНИЛ-L- -АЛАНИНА В СМЕСЯХ ВОДА-ОРГАНИЧЕСКИЙ РАСТВОРИТЕЛЬ ПРИ 298.15 К. Журнал физ. Химии. 82/9 (2008) 1744-1748. http://elibrary.ru/item.asp?id=11155039
  19. V.I. Smirnov, V.G. Badelin, The Thermochemistry of Solution of L-a-Alanyl-L-a-Alanine in Water–Alcohol Mixtures at 298.15 K. Russ. J. Phys. Chem. A, 82/7 (2008)1206–1210. https://link.springer.com/article/10.1134/S0036024408070273
  20. V.I. Smirnov, V.G. Badelin, Enthalpies of solution of l-threonine in a (water + alcohol) mixture at 298.15K. Thermochim. Acta 495 (2009) 90–94. http://dx.doi.org/10.1016/j.tca.2009.06.005.
  21. V.I. Smirnov, V.G. Badelin, Enthalpies of solution of DL-a-Alanyl-DL-a-Valine in aqueous solution of amides at 298.15K. Thermochim. Acta 485 (2009) 72–75.    http://dx.doi.org/10.1016/j.tca.2008.12.016.  
  22. E.V. Ivanov, V.I.Smirnov. Water as a solute in aprotic dipolar solvents. 1. D2O–H2O solute isotope effects on the enthalpy of water dissolution in acetone, tetrahydrofuran and 1,4-dioxane at 298.15K. Thermochim. Acta 511 (2010) 194–197.  http://dx.doi.org/10.1016/j.tca.2010.07.017.
  23. V.I. Smirnov, V.G. Badelin, Enthalpies of L-threonine dissolution in some aqueous amides at 298.15K. Thermochim. Acta. 551 503-504 (2010) 97–99. http://dx.doi.org/10.1016/j.tca.2010.03.014
  24. E.V. Ivanov, V.I.Smirnov. Water as a solute in aprotic dipolar solvents. 2. D2O–H2O solute isotope effects on the enthalpy of water dissolution in nitromethane, acetonitrile and propylene carbonate at 298.15K. Thermochim. Acta 511 (2010) 198–201. http://dx.doi.org/10.1016/j.tca.2010.09.013.
  25.  V.I. Smirnov, V.G. Badelin, Enthalpies of solution of glycylglycine in water–organic solvent media at 298.15K. Thermochim. Acta 501 (2010) 55–58.   http://dx.doi.org/10.1016/j.tca.2010.01.006
  26. V.G. Badelin, V.I. Smirnov. The Dependence of the Enthalpy of Solution of L-Methionine on the Composition of Water–Alcohol Binary Solvents. Russ. J. Phys. Chem. A, 84 (2010) 1163–1168. https://link.springer.com/article/10.1134/S0036024410070150
  27. E.V. Ivanov, V.I.Smirnov. Water as a solute in aprotic dipolar solvents: 3. D2O–H2O solute isotope effects on the enthalpy of water dissolution in dimethylsulphoxide, N,N-dimethylformamide and N,N-dimethylacetamide at 298.15 K. Thermochimica Acta 526 (2011) 257–261. http://citeweb.info/20110861499
  28. V.G. Badelin, V.I. Smirnov. Dependence of the Solution and Transfer Enthalpies of DL-α-Alanyl-DL-α-Asparagine on the Composition of Water–Amide Binary Solvents at 298.15 K. Russ. J. Phys. Chem. A, 85 (2011) 944–947. https://link.springer.com/article/10.1134/S0036024411060082
  29. V.I. Smirnov, V.G. Badelin, Enthalpies of solution of dl-α-alanyl-dl-α-asparagine in aqueous alcohols at 298.15K. Thermochim. Acta 512 (2011) 55–58.    http://dx.doi.org/10.1016/j.tca.2010.08.022
  30.  V.I. Smirnov, V.G. Badelin. Influence of the composition of aqueous-alcohol solvents on the thermodynamic characteristics of L-phenylalanine dissolution at 298.15 K. Thermochim. Acta 526 (2011) 46–49. http://dx.doi.org/10.1016/j.tca.2011.08.022
  31. V.I. Smirnov, V.G. Badelin. Dependence of enthalpies of dissolution of β-alanyl-β-alanine on the composition of (water + alcohol) mixtures at 298.15 K. Thermochim. Acta 524 (2011) 35– 38.  http://dx.doi.org/10.1016/j.tca.2011.06.008
  32. V.I. Smirnov, V.G. Badelin, Enthalpies of solution of glycylglycylglycine in aqueous solution of amides at 298.15K. Thermochim. Acta 520 (2011) 153–155. http://dx.doi.org/10.1016/j.tca.2011.02.039
  33. V.G. Badelin, V.I. Smirnov. Effects of Water–Alcohol Binary Solvents on the Thermochemical Characteristics of L-Tryptophane Solution at 298.15 K. Russ. J. Phys. Chem. A, 87 (2013) 40-43. https://link.springer.com/article/10.1134/S0036024413010020
  34. V.I. Smirnov, V.G. Badelin. Enthalpies of solution of β-alanyl-β-alanine in aqueous solution of amides at 298.15 K. Thermochim. Acta 536 (2012) 74– 76. http://dx.doi.org/10.1016/j.tca.2012.02.028
  35. V.I. Smirnov, V.G. Badelin. Influence of the composition of aqueous-alcohol solvents on thermodynamic characteristics of dl-α-alanyl-dl-norleucine dissolution at 298.15 K. Thermochim. Acta 544 (2012) 43– 46. http://dx.doi.org/10.1016/j.tca.2012.06.014
  36. V.I. Smirnov, V.G. Badelin. Thermochemistry of the Dissolution of DL-α-Alanyl-DL-Norleucine in Aqueous Solutions of Amides at 298.15 K. Russ. J Phys. Chem. A, 87 (2013) 1793–1797. https://link.springer.com/article/10.1134/S0036024413110204
  37. V.I. Smirnov, V.G. Badelin. Thermochemistry of the Dissolution of DL-α-Alanyl-DL-Norleucine in Aqueous Solutions of Amides at 298.15 K. Russ. J Phys. Chem. A, 87 (2013) 1793–1797. https://link.springer.com/article/10.1134/S0036024413110204
  38. V.I. Smirnov, V.G. Badelin. Enthalpy Characteristics of Dissolution of L-Tryptophan in Water + Formamides Binary Solvents at 298.15 K. Russ. J. Phys. Chem. A, 87 (2013) 1165–116. https://link.springer.com/article/10.1134/S0036024413070285
  39. V.I. Smirnov, V.G. Badelin. Enthalpies of solution of L-phenylalanine in aqueous solution of amides at 298.15 K. Thermochim. Acta 551 (2013) 145– 148. http://dx.doi.org/10.1016/j.tca.2012.11.004
  40. V.I. Smirnov, V.G. Badelin. Thermochemistry of the solution of β-alanine in (H2O + alcohol) mixtures at 298.15 K. Thermochim. Acta 565 (2013) 202– 204. http://dx.doi.org/10.1016/j.tca.2013.05.012
  41. V.I. Smirnov, V.G. Badelin. Effect of the Composition of a Water–Alcohol Solvent on the Thermodynamics of Dissolution of DL-α-Alanyl-β-Alanine at 298.15 K. Russ. J. Phys. Chem. A, 88 (2014) 2087–2090. https://link.springer.com/article/10.1134/S0036024414120310
  42. V.I. Smirnov, V.G. Badelin. Enthalpies of β-Alanine Dissolution in Some Water + Organic Mixtures at 298.15 K. J. Chem. Ing. Data. 56 (2014) 1774-1780. http://dx.doi.org/10.1021/je400966q
  43. V.I. Smirnov, V.G. Badelin, Influence of the composition of water–organic mixtures and of organic solvents properties on solvation of glycyl-L-tyrosine at 298.15 K. J. Mol. Liquids. 195 (2014) 139–144. http://dx.doi.org/10.1016/j.molliq.2014.02.018
  44. V.I. Smirnov, V.G. Badelin. Dependence of the Enthalpies of Alanyl-alanine Dissolution on the Composition of Mixed Water + Acetone and Water + DMSO Solvents at 298.15 K Russ. J. Phys. Chem. A, 89 (2015)1311–1315. https://link.springer.com/article/10.1134/S0036024415080294
  45. V.G. Badelin, V.I. Smirnov. Thermodynamics of DL-Alalnyl-DL-Asparagine Dissolution in Water–Organic Mixtures at 298.15 K. Russ. J. Phys. Chem. A, 89 (2015) 1796–1800. https://link.springer.com/article/10.1134/S0036024415100039
  46. V.I. Smirnov, V.G. Badelin. Influence of the composition of water–organic mixtures and the properties of organic solvents on thermochemical characteristics of l-methionine dissolution at 298.15 K. Thermochimica Acta 616 (2015) 20–26. http://dx.doi.org/10.1016/j.tca.2015.08.006
  47. V.I. Smirnov, V.G. Badelin. Enthalpies of L-proline dissolution in aqueous solution of N, N-dimethylformamide at 293.15–308.15 K. Thermochim. Acta 606 (2015) 41–44. http://dx.doi.org/10.1016/j.tca.2015.03.007
  48. V.I. Smirnov, V.G. Badelin. Enthalpy Characteristics of the Dissolution of L-Valine in Water/Formamide Mixtures at 298.15 K. Russ. J. Phys. Chem. A, 90 (2016) 2165–2169. https://link.springer.com/article/10.1134/S0036024416110261
  49. V.I. Smirnov, V.G. Badelin. Influence of the composition of aqueous-amide solvents on enthalpic characteristics of L-proline dissolution at T= 298.15 K. J. Mol. Liquids 220 (2016) 21–25. http://dx.doi.org/10.1016/j.molliq.2016.04.033  
  50. V.I. Smirnov, V.G. Badelin. Thermochemical Characteristics of the Dissolution of D-Valine in Aqueous Solutions of Some Amides at T = 298.15 K. J. Chem. Ing. Data. 89 (2016) 1593-1780. http://dx.doi.org/10.1021/acs.jced.5b01087 
  51. V.I. Smirnov, V.G. Badelin. Enthalpy Characteristics of L-Proline Dissolution in Certain Water–Organic Mixtures at 298.15 K. Russ. J. Phys. Chem. A, 91 (2017) 84–88. https://link.springer.com/article/10.1134/S0036024416120037 
  52. V.I. Smirnov, V.G. Badelin. Thermochemical characteristics of 4-OH-L-proline and L-proline dissolution in (H2O + alcohol) mixtures at T=298.15 K. J. Mol. Liquids 229 (2017) 198–202. http://dx.doi.org/10.1016/j.molliq.2016.12.025 
  53. V.I. Smirnov, V.G. Badelin. Thermodynamic characteristics of trans-4-hydroxy-L-proline dissolution in some (water + amide) mixtures at T=298.15 K. Thermochim. Acta 653 (2017) 27-31. http://dx.doi.org/10.1016/j.tca.2017.03.022

 

Основные этапы научно-педагогической деятельности

1973-1978 Ивановский энергетический институт им.В.И.Ленина, инженер-электрик;

1979-1980 Ивановский НИИПИК, старший инженер;

1981-1987 Институт химии неводных растворов, младший научный сотрудник;

1987- год защиты кандидатской диссертации, кандидат химических наук;

1987-1990- старший научный сотрудник;

1989- присвоение ученого звания «Старший научный сотрудник»;

1990-1992 – заведующий СКТБ «Жидкофазные материалы»;

1992 - настоящее время – старший научный сотрудник лаборатории 1-1