Chemistry and practical application of macrocyclic compounds

Scope of research: 

The aim of the studies consists in developing novel approaches to synthesis, investigation of the interconnections between the structure and properties of macroheterocyclic compounds of different nature (porphyrins and their analogues, calyx[n]pyrroles, calyx[n]arenes, etc.) as the basis for designing new substances and materials with a tailor-made architecture and practically relevant functional (redox, acid base, spectral-luminescent, sensor, receptor, light conversion, photosensitizing, antibacterial and other) properties.

Key words: 
Molecular recognition
Porphyrins
Photoinduced electron transfer
Photosensitizer
Cooperation: 

- Leibnitz Institute of Photonic Technology (Jena, Germany);

- Catholic University of Leuven (Leuven, Belgium);

- B.I. Stepanov Institute of Physics of the National Academy of Sciences (Minsk, Belarus);

- Institute of Physical and Organic Chemistry of the Southern Federal University (Rostov-on-Don, Russia);

- University of Turin (Turin, Italy);

- Semenov Research Center of Chemical Physics (Moscow, Russia);

- Privolzhsky Research Medical University (Nizhny Novgorod, Russia).

Publications: 

1. Koifman O.I. et al. Macroheterocyclic Compounds - a Key Building Block in New Functional Materials and Molecular Devices // Macroheterocycles. - 2020. – V.13. – P. 311-467. DOI: 10.6060/mhc200814k.

2. Likhonina A.E., Mamardashvili G.M., Khodov I.A., Mamardashvili N.Z. Synthesis and Design of Hybrid Metalloporphyrin Polymers Based on Palladium (II) and Copper (II) Cations and Axial Complexes of Pyridyl-Substituted Sn(IV)Porphyrins with Octopamine // Polymers. – 2023. – V. 15(4). – Art. 1055. DOI: 10.3390/polym15041055.

3. Bichan N.G., Tsaturyan A.A., Ovchenkova E.N., Kudryakova N.O., Gostev F.E., Shelaev I.V., Aybush A.V., Nadtochenko V.A., Lomova T. N. Donor–acceptor interac-tions of gold(III) porphy-rins with cobalt(II) phthal-ocyanine: chemical struc-ture of products, their spec-tral characterization and DFT study // Dalton Trans. – 2022. - V. 51. – Art. 9072. DOI: 10.1039/D2DT01182D.

4. Bichan N.G., Ovchenkova E.N., Ksenofontov A.A., Mozgova V.A., Gruzdev M.S., Chervonova U.V., Shelaev I.V., Lomova T.N. Meso-carbazole substituted porphyrin complexes: synthesis and spectral properties according to experiment, DFT calculations and the prediction by machine learning methods // Dyes and Pigments. – 2022. – V. 204. – Art. 110470. DOI: 10.1134/S0036023622030147.

5. Mamardashvili G.M., Kaigorodova E. Yu., Lebedev I.S., Mamardashvili N.Z. Axial complexes of Sn (IV)-tetra (4-sulfophenyl) porphyrin with azorubine in aqueous media: fluorescent probes of local viscosity and pH indicators // Journal of Molecular Liquids. – 2022. – P. 366. – Art. 120277. DOI: 10.1016/j.molliq.2022.120277.

6. Rusanov A.I., Dmitrieva O.A., Mamardashvil N.Zh., Tetko I.V. More Is Not Always Better: Local Models Provide Accurate Predictions of Spectral Properties of Porphyrins // International Journal of Molecular Sciences. – 2022. - V. 23. – Art. 1201. DOI: 10.3390/ijms23031201.

7. Lomova T.N. Recent progress in organometallic porphyrin-based molecular materials for optical sensing, light conversion, and magnetic cooling // Applied Organometallic Chemistry. – 2021. V. 35. – Art. e6254. DOI: 10.1002/aoc.6254.

8. Kiselev A.N., Zaitseva S.V., Zdanovich S.A., Shagalov E.V., Aleksandriysky V.V., Syrbu S.A., Koifman O.I. Direct Cobalt-Catalyzed Phosphorylation of Porphyrins // ChemistrySelect. – 2021. – V. 6 (43). – Art. 12188. DOI: 10.1002/slct.202102728.

9. Sheinin V.B., Kulikova O.M.  pH-controlled solubilization of photosensitizer tetraphenylporphyrin // Dyes and Pigments. – 2021. – P. 194. – Art. 109589. DOI: 10.1016/j.dyepig.2021.109589.

10. Tesakova M.V., Kuzmin S.M., Parfenyuk V.I. Electrodeposition of films of individual 5,10,15,20-tetrakis(3-aminophenyl)porphyrin metal complexes and their composite for electrocatalytic oxygen reduction // Inorganic Chemistry Communications. – 2022. - P.135. – Art.109106. DOI: 10.1016/j.inoche.2021.109106.